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Mechanism of the elementary event in reactions of alcohol radicals with ferricyanide

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Literature cited

  1. R. R. Dogonadze and A. M. Kuznetsov, “Kinetics of chemical reactions in polar solvents,” Results of Science, Physical Chemistry, Kinetics Series [in Russian], Vol. 2, VINITI, Moscow (1973).

    Google Scholar 

  2. B. M. Berdnikov, “Energetics of the oxidation of alcohol radicals in aqueous solution,” Zh. Fiz. Khim., 51, No. 6, 1396–1398 (1977).

    Google Scholar 

  3. R. A. Marcus, “On the theory of oxidation-reduction involving electron transfer,” J. Chem. Phys., 24, No. 5, 966–978 (1956).

    Google Scholar 

  4. A. A. Ovchinnikov and M. Ya. Ovchinnikova, “The theory of elementary reactions of electron transport in a polar liquid,” Zh. Eksp. Teor. Fiz., 56, No. 4, 1278–1289 (1969).

    Google Scholar 

  5. M. A. Vorotyntsev, R. R. Dogonadze, and A. M. Kuznetsov, “Probability of the transfer of charge in a polar medium with continuous vibration spectrum,” Dokl. Akad. Nauk SSSE, 195, No. 5, 1135–1138 (1970).

    Google Scholar 

  6. Yu. I. Kharkats, “Calculation of the rate constant of electron transport in a polar medium,” Elektrokhimiya, 12, No. 4, 592–594 (1976).

    Google Scholar 

  7. B. N. Figgis, M. Gerloch, and R. Mason, “The crystallography and paramagnetic anisotropy of potassium ferricyanide,” Proc. Roy. Soc., 309, No. 1496, 91–118 (1969).

    Google Scholar 

  8. J. D. Swalen, “Structure and potential barrier to hindered rotation in methyl alcohol,” J. Chem. Phys., 23, No. 9, 1739–1740 (1955).

    Google Scholar 

  9. A. C. Hopkinson and J. G. Csizmadia, “An ab initio study of the effect of substitutions on protonation of the carbonyl group,” Can. J. Chem., 52, No. 4, 546–554 (1974).

    Google Scholar 

  10. A. I. Kitaigorodskii, Organic Crystal Chemistry [in Russian], Izd. Akad. Nauk SSSR, Moscow (1955).

    Google Scholar 

  11. L. J. Bellamy, Infrared Spectra of Complex Molecules, Halsted Press (1975).

  12. A. M. Kuznetsov, “Calculation of the probability of electron transport in polar medium,” Elektrokhimiya, 7, 1067–1069 (1971).

    Google Scholar 

  13. J. A. Lane and R. Saxton, “Dielectric dispersion in pure polar liquids at very high radio frequencies. I. Measurement on water, methyl, and ethyl alcohols,” Proc. Roy. Soc., A213, No. 1114 400–408 (1952).

    Google Scholar 

  14. E. Clementi and C. Roetti, “Roothaan-Hartree-Fock atomic wave functions,” Atomic Data and Nuclear Tables, 14, No. 3–4 (1974).

  15. R. G. Shulman and S. Sugano, “Molecular orbital analysis of iron group cyanides,” J. Chem. Phys., 42, No. 1, 39–43 (1965).

    Google Scholar 

  16. R. J. Kurland and B. R. McGarvey, “Isotropic NMR shifts in transition-metal complexes: the calculation of the Fermi contact and pseudocontact terms,” J. Magn. Eesonance, 2, No. 3, 286–301 (1970).

    Google Scholar 

  17. V. M. Berdnikov, L. L. Makarshin, and L. I. Murza, “Exchange interaction between the stable nitroxide radical and ferricyanide in aqueous solution,” Zh. Strukt. Khim., 18, No. 6 (1977).

  18. F. S. Sarvarov, “Spin effect in the kinetics of radical recombination,” Candidate's Dissertation, Novosibirsk (1976).

  19. K. P. Mishchenko and A. A. Rvdel' (editors), Concise Handbook of Physicochemical Quantities [in Russian], Khimiya, Leningrad (1974).

    Google Scholar 

  20. Landolt-Börnstein, Eigenschaften der Materie in ihren aggregat Zustanden,” Transportphenomene I., Vol. 2, No. 5, Springer-Verlag, Berlin-Heidelberg-New York (1969).

    Google Scholar 

  21. G. E. Adams and R. L. Wilson, “Pulse radiolysis studies on the oxidation of organic radicals in aqueous solutions,” Trans. Farad. Soc., 65, No. 11, 2981–2987 (1969).

    Google Scholar 

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Published to stimulate discussion.

Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 13, No. 6, pp. 747–754, November–December, 1977.

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Berdnikov, V.M., Dogonadze, R.R. Mechanism of the elementary event in reactions of alcohol radicals with ferricyanide. Theor Exp Chem 13, 564–569 (1978). https://doi.org/10.1007/BF00520806

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