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Introduction of electrochemically activated carbon dioxide in halogen-containing polymers

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Abstract

The possibility of electrochemical carboxylation of halogen-containing polymers by using carbon dioxide has been shown on the example of polyvinyl chloride and polyvinyl bromide. The process proceeds via the substitution of halogen atoms by carboxylic groups; this leads to the formation of the corresponding polyacrylic acid copolymers. The influence of various factors (the nature of the medium and of the electrode materials, the electrolysis mode, etc.) on the degree of carboxylation of the polymers has been studied.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of Ukraine, Kiev

    V. G. Koshechko, V. E. Titov & D. V. Sednev

Authors
  1. V. G. Koshechko
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  2. V. E. Titov
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  3. D. V. Sednev
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Additional information

Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 29, No. 1, pp. 57–62, January–February, 1993.

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Koshechko, V.G., Titov, V.E. & Sednev, D.V. Introduction of electrochemically activated carbon dioxide in halogen-containing polymers. Theor Exp Chem 29, 41–44 (1994). https://doi.org/10.1007/BF00520260

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  • DOI: https://doi.org/10.1007/BF00520260

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