Abstract
X-ray diffraction analysis data has been used to calculate the electron-density distribution of a squared crystal of hydrated antimony pentoxide during sorption of water, nitric acid, and strontium cations. It has been shown that absorption of water and acid molecules causes reversible changes of the anionic framework of the ionite. Sorption of divalent cations is accompanied by irreversible phase transformations in the sorbent structure, which is also the cause of the particularly strong retention of particles of the material absorbed.
Similar content being viewed by others
Literature cited
V. V. Vesely and V. Pekarek, “Synthetic inorganic ion exchangers. 1. Hydrous oxides and acidic salts of multivalent metals,” Talanta, 19, No. 3, 219–262 (1972).
B. P. Nikol'skii and P. G. Romonov, eds., Ionites in Chemical Engineering [in Russian], Khimiya, Leningrad (1982).
V. G. Novikov, F. A. Belinskaya, and E. A. Materova, “Structure and ion exchange properties of a crystalline antimony oxide cationite. Exchange of singly charged ions,” Vestn. Leningrad Un-ta, No. 4, 29–35 (1971).
B. N. Laskorin, L. I. Bondarenko, V. V. Strelko, et al., “Features of sorption of doubly charged cations by ionites based on antimonic acid,” Dokl. Akad. Nauk SSSR, 229, No. 6, 1411–1414 (1976).
L. I. Bondarenko, T. N. Vernitskaya, A. V. Gette, and A. A. Chuiko, “Investigation of the kinetics of strontium sorption by an antimony phosphosilicate cationite,” Radiokhimiya, 26, No. 1, 40–43 (1983).
G. P. Safro, V. M. Ogenko, and A. A. Chuiko, “Investigation of the thermodesorption method for development and investigation of solid-state primary measuring transducers of gas alarms and gas analyzers,” Summaries of Reports of All-Union Scientific and Technical Conference on New Physical Principles in Analytical Instrument Design, Kiev, Sept. 30–Oct. 2, 1980, Moscow (1980), p. 41.
G. B. Bokii and M. A. Porai-Koshits, X-Ray Diffraction Analysis [in Russian], Khimiya, Moscow (1964).
M. Burger, Structure of Crystals in Vector Space [Russian translation], IL, Moscow (1961).
B. K. Vainshtein, “Numerical relations in Fourier series for electron densities of crystals,” Zh. Éksp. Teor. Fiz., 27, No. 1, 44–61 (1954).
T. N. Polynova and M. A. Porai-Koshits, “Structures of pentavalent antimony compounds,” Zh. Strukt. Khim., 7, No. 4, 642–656 (1966).
L. I. Bondarenko and V. V. Strel'ko, “Investigations of the porous gel structure of antimony-silicate acid,” Kolloidn. Zh., 46, No. 6, 1198–1201 (1984).
Author information
Authors and Affiliations
Additional information
Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 22, No. 2, pp. 229–234, March–April, 1986.
Rights and permissions
About this article
Cite this article
Bondarenko, L.I., Safro, G.P. & Chuiko, A.A. Structural conversions of hydrated antimony pentoxide during absorption of cations and polar adsorbates. Theor Exp Chem 22, 215–218 (1986). https://doi.org/10.1007/BF00519198
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00519198