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Reaction of quinoxaline with benzopyridines in acetic anhydrides in the presence of Zn dust

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction between quinoxaline and benzopyridine in acetic anhydride in the presence of zinc dust gives a quinoxaline anion and a benzopyridine N-acetyl radical, which recombine to give the previously unknown N-acetyl dihydrobenzo-pyridine derivative of 1,2-dihydroquinoxaline. Under these conditions, quinoxaline alone gives 1,4-diacetyl-1,4-dihydroquinoxaline and 1-acetyl-2-(1,2-dihydroquinoxalyl-2)-1,2-dihydroquinoxaline.

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Authors and Affiliations

  1. Dniepropetrovsk Engineering-Construction Institute, 320361, Dniepropetrovsk

    A. K. Sheinkman, Kh. Ya. Lopatinskaya & P. B. Terent'ev

  2. Institute of Physicoorganic Chemistry and Academy of Sciences of the Ukrainian SSR, 340114, Donetsk

    A. K. Sheinkman, Kh. Ya. Lopatinskaya & P. B. Terent'ev

Authors
  1. A. K. Sheinkman
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  2. Kh. Ya. Lopatinskaya
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  3. P. B. Terent'ev
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Additional information

Previous communication, [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 967–973, July, 1985.

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Sheinkman, A.K., Lopatinskaya, K.Y. & Terent'ev, P.B. Reaction of quinoxaline with benzopyridines in acetic anhydrides in the presence of Zn dust. Chem Heterocycl Compd 21, 805–810 (1985). https://doi.org/10.1007/BF00519152

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  • DOI: https://doi.org/10.1007/BF00519152

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