Theoretical and Experimental Chemistry

, Volume 17, Issue 4, pp 399–409 | Cite as

The nature of the chemical bond in the carbides and nitrides of d metals

  • A. I. Kharlamov
Article

Keywords

Carbide Nitrides Chemical Bond 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    V. G. Aleshin, A. I. Kharlamov, and T. S. Bartnitskaya, “Character of interatomic interaction in metal-like and covalent nitrides,” Izv. Akad. Nauk SSSR. Neorg. Mater., 15, No. 4, 677–680 (1979).Google Scholar
  2. 2.
    A. I. Kharlamov, V. G. Aleshin, V. M. Prokopenko, and N. V. Kirillova, “Relation between electronic and physicochemical characteristics of the carbides and nitrides of d metals of the fourth period,” Teor. Eksp. Khim., 16, No. 5, 730–734 (1980).Google Scholar
  3. 3.
    V. G. Aleshin, A. I. Kharlamov, and V. M. Prokopenko, “X-ray photoelectron spectra of metal-like carbides,” Izv. Akad. Nauk SSSR, Neorg. Mater., 17, No. 3, 550–553 (1981).Google Scholar
  4. 4.
    V. V. Nemoshkalenko, M. M. Kindrat, V. P. Krivitskii, B. P. Mamko, V. M. Prokopenko, and A. I. Kharlamov, “X-ray emission and photoelectron spectra and the nature of the bond in titanium carbides and nitrides,” Metallofizika, 3, No. 3, 37–43 (1981).Google Scholar
  5. 5.
    V. V. Nemoshkalenko, M. M. Kindrat, V. P. Krivitskii, B. P. Mamko, B. K. Ostafiichuk, A. I. Senkevich, and A. I. Kharlamov, “X-ray emission and photoelectron spectra of carbon and chromium in its carbides,” Izv. Akad. Nauk SSSR, Neorg. Mater., 17, No. 6, 996–999 (1981).Google Scholar
  6. 6.
    V. V. Nemoshkalenko, M. M. Antonova, L. S. Voskrekasenko, V. P. Krivitskii, L. I. Nikolaev, A. I. Kharlamov, and A. P. Shpak, “Synthesis and x-ray spectral investigation of the electronic structure of hydrides and hydridonitrides,” Izv. Akad. Nauk SSSR, Neorg. Mater., 14, No. 9. 1641–1644 (1978).Google Scholar
  7. 7.
    V. V. Nemoshkalenko, V. G. Aleshin, Yu. N. Kucherenko, L. M. Sheludchenko, and A. I. Kharlamov, “Investigation of the electronic structure of compounds of titanium and vanadium by the wave scattering method,” Dokl. Akad. Nauk SSSR, 252, No. 3, 602–606 (1980).Google Scholar
  8. 8.
    E. A. Zhurakovskii, Electronic Structure of Refractory Compounds [in Russian], Naukova Dumka, Kiev (1976).Google Scholar
  9. 9.
    P. V. Gel'd, V.A. Tskhai, G. P. Shveikin, and V. A. Perelyaev, “Effect of M-M interactions on the structural and thermodynamic characteristics of the carbles, nitrides, and oxides of metals of subgroups IVa and Va,” Izv. Akad. Nauk SSSR, Neorg. Mater., 3, No. 10, 1835–1841 (1967).Google Scholar
  10. 10.
    V. A. Tskhai, “Screening of Me-Me bonds and its effect on the properties of cubic oxides and carbides of the metals of subgroups IVa and Va and their mutual solutions,” Tr. Inst. Khim. UNTs Akad. Nauk SSSR, No. 36, 25–32 (1978).Google Scholar
  11. 11.
    S. A. Nemnonov and K. M. Kolobova, “X-ray spectra, electronic structure, and characteristics of metallic compounds of titanium,” Fiz. Met. Metalloved., 22, No. 5, 680–692 (1966).Google Scholar
  12. 12.
    S. A. Nemnonov, “The K and L spectra of metal-like compounds of titanium,” Fiz. Met. Metalloved., 24, No. 2, 268–271 (1967).Google Scholar
  13. 13.
    A. S. Shulakov, T. M. Zimkina, V. N. Fomichev, and V. S. Neshpor, “X-ray spectral investigation of the carbides and nitrides of transition metals of groups 4 and 5,” Fiz. Tverd. Tela, 18, No. 3, 783–796 (1976).Google Scholar
  14. 14.
    S. A. Nemnonov, É. Z. Kurmaev, K. M. Kolobova, and A. Z. Men'shikov, “X-ray spectra and electronic structure of metal-like compounds of transition metals,” Fiz. Met. Metalloved., 25, No. 6, 1064–1070 (1968).Google Scholar
  15. 15.
    L. Ramquist, K. Hamrin, G. Johansson, A. Fahlman, and C. Nordling, “Charge-transfer in transition metal carbides and related compounds. Studies by ESCA,” J. Phys. Chem. Solids, 30, No. 7, 1835–1847 (1969).Google Scholar
  16. 16.
    L. Ramquist, K. Hamrin, G. Johansson, U. Gelius, and C. Nordling, “VC, NbC, and TaC with varying carbon content studied by ESCA,” J. Phys. Chem. Solids, 31, No. 8, 2669–2672 (1970).Google Scholar
  17. 17.
    L. Ramquist, R. Ekstig, E. Källne, E. Noreland, and R. Manne, J. Phys. Chem. Solids, 30, No. 7, 1849–1860 (1969).Google Scholar
  18. 18.
    V. G. Bhide and M. K. Bahe, “X-ray K-absorption edge of niobium in some niobium compounds,” J. Phys. C: Solid State Phys., 6, No. 13, 2241–2248 (1973).Google Scholar
  19. 19.
    L. I. Johansson, A. L. Hagström, B. E. Jacobson, and S. B. Hagstrom, “ESCA studies of core level shifts and valence bond structure carbide,” J. Electron Spectroscopy and Related Phenomena, 10, No. 1, 259–271 (1977).Google Scholar
  20. 20.
    V. V. Nemoshkalenko, V. P. Krivitskii, A. P. Nesenjuk, L. I. Nikolajev, and A. P. Shpak, “X-ray band spectra and electronic structure of carbides and nitrides of zirconium, niobium, and molybdenum,” J. Phys. Chem. Solids, 36, No. 1, 277–281 (1975).Google Scholar
  21. 21.
    A. L. Ivanovskii, V. A. Gubanov, E. Z. Kurmaev, A. L. Hagström, S. E. Karlsson, and L. I. Johansson, “Interpretation of ESCA spectra for nonstoichiometric titanium carbides on the basis of MO LCAO calculations,” J. Electron Spectroscopy and Related Phenomena, 16, No. 6, 415–423 (1979).Google Scholar
  22. 22.
    V. A. Gubanov, É. Z. Kurmaev, and A. K. Chirkov, “Application of cluster molecular orbital methods to the investigation of the electronic structure of compounds of vanadium and titanium in the solid state,” Tr. Inst. Khim. UNTs Akad. Nauk SSSR, No. 36, 7–24 (1978).Google Scholar
  23. 23.
    K. Siegbahn, C. Nordling, A. Fahlman, et al., Electron Spectroscopy [Russian translation], Mir, Moscow (1971).Google Scholar
  24. 24.
    Kh. M. Minachev, G. V. Antoshin, and E. S. Shpiro, “Application of photoelectron Spectroscopy for the investigation of catalysis and adsorption,” Usp. Khim., 47, No. 12, 2097–2133 (1978).Google Scholar
  25. 25.
    O. M. Hercules, “Electron Spectroscopy. 2. X-ray photoexcitation,” Analyt. Chem., 44, No. 13, 106–111 (1972).Google Scholar
  26. 26.
    R. A. Barinskii and V. I. Nefedov, X-Ray Spectral Determination of the Charges of Atoms in Molecules [in Russian], Nauka, Moscow (1966).Google Scholar
  27. 27.
    V. V. Nemoshkalenko, L. M. Sheludchenko, Yu. N. Kucherenko, and V. G. Aleshin, “Dependence of the binding energy of the core electrons on the effective charges on the atoms in crystals,” in: Electron Spectroscopy. Materials of Third All-Union Conference [in Russian], Kiev (1979), pp. 21–25.Google Scholar
  28. 28.
    C. A. Thomas, Photoelectron and Auger Spectroscopy, New York-London (1975).Google Scholar
  29. 29.
    K. B. Yatsimirskii, V. V. Nemoshkalenko, V. G. Aleshin, Yu. P. Nazarenko, V. V. Zhilinskaya, and A. I. Senkevich, “Investigation of some pentacyanide complexes of cobalt by x-ray electron Spectroscopy,” in: Electron Spectroscopy. Materials of Third All-Union Conference [in Russian], Kiev (1979), pp. 10–16.Google Scholar
  30. 30.
    O. V. Krylov, Catalysis by Nonmetals [in Russian], Khimiya, Leningrad (1967).Google Scholar
  31. 31.
    W. B. Pearson, “Explanation and prediction of the most important electronic characteristics of semiconductors on the basis of data on chemical bonds,” Zh. Vses. Khim. Obshch., 5, No. 5, 493–497 (1960).Google Scholar
  32. 32.
    L. M. Sheludchenko, Yu. N. Kucherenko, V. G. Aleshin, and V. V. Nemoshkalenko, Electronic tructure of the Carbides, Nitrides, and Oxides of Titanium and Vanadium [in Russian], Kiev (1979), (Inst. Metallofiz. Akad. Nauk UkrSSR, Preprint 79.5).Google Scholar
  33. 33.
    A. I. Kharlamoy and N. V. Kirillova, “Activity of zirconium, vanadium, and ferrous nitrides in the oxidation of carbon monoxide,” React. Kinet. Catal. Lett., 15, No. 3, 345–350 (1980).Google Scholar
  34. 34.
    I. B. Bersuker, Electronic Structure and Characteristics of Coordination Compounds [in Russian], Khimiya, Leningrad (1976).Google Scholar
  35. 35.
    V. Ern and A. Switendick, “Electronic band structure of TiC, TiN, and TiO,” Phys. Rev. A, 137, No. 6, 1927–1936 (1965).Google Scholar
  36. 36.
    R. C. Lye and E. M. Logothetis, “Optical properties and structure of titanium carbide,” Phys. Rev., 147, No. 2, 622–635 (1966).Google Scholar
  37. 37.
    L. Pauling, “The modern theory of valency,” J. Chem. Soc., No. 9, 1461–1467 (1948).Google Scholar

Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • A. I. Kharlamov
    • 1
  1. 1.Institute of Problems in Materials ScienceAcademy of Sciences of the Ukrainian SSRKiev

Personalised recommendations