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Electrochemical modeling of the oxidative dehydrogenation of 4H-thiopyrans

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The oxidation of substituted 4H-thiopyrans on a rotating platinum disk electrode with a ring in acetonitrile was accomplished for the first time. It was established that the dehydrogenation of both tri- and pentasubstituted thiopyrans proceeds via a scheme involving the successive transfer of an electron, a proton, and an electron (an EPE process); 4H-thiopyrans are oxidized more readily than the corresponding oxygen analogs.

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Authors and Affiliations

  1. N. G. Chernyshevskii Saratov State University, 410601, Saratov

    I. M. Sosonkin, A. N. Domarev, N. I. Kozhevnikova & V. G. Karchenko

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  1. I. M. Sosonkin
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  2. A. N. Domarev
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  3. N. I. Kozhevnikova
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  4. V. G. Karchenko
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 318–320, March, 1984.

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Sosonkin, I.M., Domarev, A.N., Kozhevnikova, N.I. et al. Electrochemical modeling of the oxidative dehydrogenation of 4H-thiopyrans. Chem Heterocycl Compd 20, 253–255 (1984). https://doi.org/10.1007/BF00515631

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  • DOI: https://doi.org/10.1007/BF00515631

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