Chemistry of Heterocyclic Compounds

, Volume 27, Issue 12, pp 1312–1315 | Cite as

Free-radical intermediates in the electrochemical reduction of α,β derivatives of β-(5-nitro-2-furyl)-α-cyanoethylene

  • R. A. Gavar
  • Ya. P. Stradyn'
  • L. Kh. Baumane
  • K. Enish
Article
  • 44 Downloads

Abstract

It was found by cyclic voltammetry and ESR that the excitation of the molecules of α,Β derivatives of Β-(5-nitro-2-furyl)-α-cyanoethylene in the radical-anion state by one-electron electrochemical reduction promotes chemical transformation of the other reaction centers, while preserving the nitrofuran group.

Keywords

Organic Chemistry Reaction Center Cyclic Voltammetry Chemical Transformation Electrochemical Reduction 

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Copyright information

© Plenum Publishing Corporation 1992

Authors and Affiliations

  • R. A. Gavar
    • 1
    • 2
  • Ya. P. Stradyn'
    • 1
    • 2
  • L. Kh. Baumane
    • 1
    • 2
  • K. Enish
    • 1
    • 2
  1. 1.Institute of Organic SynthesisLatvian Academy of SciencesRiga
  2. 2.Central Institute of Organic ChemistryBerlin Academy of SciencesBerlin-Adlershof

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