Skip to main content
SpringerLink
Log in

X-ray emission spectroscopy and electronic structure of heterocyclic compounds. 1. Furan

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The electronic structure of the furan molecule was investigated by x-ray spectroscopy. A quantum-chemical calculation (ab initio) was undertaken, and the results were compared with the experimental data. The interpretation of the x-ray spectra of the molecule, the carbon atoms of which have a different energy position for the 1s levels, is discussed in detail. The electronic transitions from the MO to these core levels are clearly recorded in the carbon x-ray spectrum. It was shown experimentally that the HOMO is an orbital in which the electron density is localized at the carbon atoms.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature Cited

  1. V. Von Niessen, W. P. Kraemer, and L. S. Cederbaum, J. Electron Spectr. Related Phenomena, 8, 179 (1976).

    Google Scholar 

  2. K. Kimura, S. Katsumata, Y. Achiba, et al., Handbook of the Hel Photoelectron Spectra of Fundamental Organic Molecules, Japan Sci. Soc. Press, Tokyo; Halsted Press, New York (1981), p. 208.

    Google Scholar 

  3. R. R. Gupta (ed.), Physical Methods in Heterocyclic Chemistry, Wiley (1984), p. 231.

  4. U. Gelius, C. J. Allan, G. Johansson, et al., Phys. Scripta, 3, 237 (1971).

    Google Scholar 

  5. S. A. Chambers and T. D. Thomas, J. Chem. Phys., 67, 2596 (1977).

    Google Scholar 

  6. L. N. Mazalov and V. D. Yumatov, Electronic Structure of Extradants [in Russian], Nauka, Novosibirsk (1984), p. 29.

    Google Scholar 

  7. L. N. Mazalov, V. D. Yumatov, and A. V. Okotrub, Izv. Akad. Nauk SSSR. Ser. Fiz., 49, 1483 (1985).

    Google Scholar 

  8. V. D. Yumatov, A. V. Okotrub, L. N. Mazalov, et al., Zh. Strukt. Khim., 26, No. 4, 59 (1985).

    Google Scholar 

  9. A. Savitsky and M. J. E. Golay, Anal. Chem., 36, 1627 (1964).

    Google Scholar 

  10. D. Briggs and M. P. Sich (eds.), Surface Analysis by Auger and Photoelectron Spectroscopy [Russian translation], Mir, Moscow (1987), p. 497.

    Google Scholar 

  11. A. V. Okotrub, V. D. Yumatov, and L. N. Mazalov, Dokl. Akad. Nauk SSSR, 275, 1456 (1984).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Organic Synthesis, Latvian Academy of Sciences, Riga

    V. D. Yumatov, V. V. Murakhtanov, A. V. Okotrub, N. P. Erchak & É. Lukevits

Authors
  1. V. D. Yumatov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. V. Murakhtanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Okotrub
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. P. Erchak
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. É. Lukevits
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1631–1635, December, 1991.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yumatov, V.D., Murakhtanov, V.V., Okotrub, A.V. et al. X-ray emission spectroscopy and electronic structure of heterocyclic compounds. 1. Furan. Chem Heterocycl Compd 27, 1308–1312 (1991). https://doi.org/10.1007/BF00515574

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00515574

Keywords

Search

Navigation