Skip to main content
SpringerLink
Log in

Synthesis and properties of symm-triazines. 3. Reactions of 2-alkyl-4,6-bistrichloromethyl-symm-triazines containing higher alkyl groups with ammonia and aliphatic amines

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of 2-alkyl-4,6-bistrichloromethyl-symm-triazines containing higher alkyl groups with ammonia or aliphatic amines results, depending on the reaction conditions, in the replacement of one or both trichloromethyl groups. On heating these symm-triazines with aqueous ammonia or dimethylamine, 2-oxo-4-amino-6-alkyl-1(3)H-symm-triazines are obtained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. O. V. Malova, T. P. Vishnyakova, I. A. Golubeva, V. I. Kelarev, and A. F. Lunin, Khim. Geterotsikl. Soedin., No. 12, 1678 (1984).

    Google Scholar 

  2. V. I. Kelarev, Ammar Dibi, A. F. Lunin, R. L. Ushakova, A. I. Mikaya, N. V. Petrova, and S. G. Shvekhgeiter, Zh. Org. Khim., 19, 2401 (1983).

    Google Scholar 

  3. C. Grundmann and G. Weisse, Chem. Ber., 84, 684 (1951).

    Google Scholar 

  4. A. Kreutzberger, Adv. Chem. Soc., 34, 208 (1962).

    Google Scholar 

  5. K. Wakabayashi, M. Tsunoda, and Y. Suzuki, J. Synth. Org. Chem. Jpn., 27, 868 (1969).

    Google Scholar 

  6. K. Wakabayashi, M. Tsunoda, and Y. Suzuki, J. Synth. Org. Chem. Jpn., 28, 252 (1970).

    Google Scholar 

  7. D. W. Kaiser, US Patent No. 2 606 904; Chem. Abstr., 47, 8774 (1953).

    Google Scholar 

  8. A. I. Finkel'shtein and E. N. Boitsov, Usp. Khim., 31, 1496 (1962).

    Google Scholar 

  9. A. R. Katritzky (editor), Physical Methods in the Chemistry of Organic Compounds [Russian translation], Mir, Moscow-Leningrad (1966), p. 594.

    Google Scholar 

  10. R. D. Spenger, Spectrochim. Acta, 21, 1543 (1965).

    Google Scholar 

  11. A. I. Finkel'shtein, Opt. Spektrosk., 5, 264 (1958).

    Google Scholar 

  12. Yu. N. Sheinker and Yu. I. Pomerantsev, Zh. Fiz. Khim., 30, 76 (1956).

    Google Scholar 

  13. V. V. Dovlatyan, K. A. Éliazyan, and A. V. Dovlatyan, Khim. Geterotsikl. Soedin., No. 7, 989 (1977).

    Google Scholar 

  14. A. Grün, US Patent No. 1 447 175; Chem. Abstr., 43, 1814 (1949).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. I. M. Gubkin Moscow Institute for the Petrochemical and Gas Industries, 117917, Moscow

    V. I. Kelarev, Ammar Dibi & A. F. Lunin

Authors
  1. V. I. Kelarev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ammar Dibi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. F. Lunin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

For communication 2, see [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1557–1563, November, 1985.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kelarev, V.I., Dibi, A. & Lunin, A.F. Synthesis and properties of symm-triazines. 3. Reactions of 2-alkyl-4,6-bistrichloromethyl-symm-triazines containing higher alkyl groups with ammonia and aliphatic amines. Chem Heterocycl Compd 21, 1284–1289 (1985). https://doi.org/10.1007/BF00515231

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00515231

Keywords

Search

Navigation