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Chemistry of Heterocyclic Compounds

, Volume 21, Issue 11, pp 1261–1264 | Cite as

Nitro- and amino-substituted 10,10-dimethyl-10-sila-2-azaanthrones

  • N. S. Prostakov
  • Islam Nazrul
  • A. V. Varlamov
Article

Abstract

Under conditions of the Mencke reaction, 10,10-dimethyl-9,10-dihydro-10-sila-2-azaanthracene is nitrated on the benzene fragment of the molecule, but the corresponding ketone is nitrated on the pyridine fragment. Dihydrosilaazaanthrone is nitrated by nitrating mixture in positions 5, 7, and 8 of the benzene fragment of the molecule. The nitro-substituted dihydrosilazaanthrones have been reduced to the corresponding amino derivatives.

Keywords

Nitrate Benzene Organic Chemistry Pyridine Ketone 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • N. S. Prostakov
    • 1
  • Islam Nazrul
    • 1
  • A. V. Varlamov
    • 1
  1. 1.P. Lumumba Peoples' Friendship UniversityMoscow

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