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Heteroadamantanes and their derivatives. 4. Synthesis of 1,3,5-triazaadamantane

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Reduction of 7-nitro-1,3,5-triazaadamantane with hydrazine hydrate in the presence of Raney nickel gave 7-hydroxyamino- and 7-amino-1,3,5-triazaadamantane, from which 7-chloro-, 7-bromo-, and 7-thiocyanato-1,3,5-triazaadamantanes were synthesized by substitutive deamination. Desulfurization of 7-thiocyanato-1,3,5-triazaadamantane in the presence of Raney nickel gave 1,3,5-triazaadamantane.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, 119435, Moscow

    A. I. Kuznetsov, V. A. Kosmakov & B. V. Unkovskii

Authors
  1. A. I. Kuznetsov
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  2. V. A. Kosmakov
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  3. B. V. Unkovskii
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Additional information

For Communication 3, see [1].

Translated from Khitniya Geterotsiklicheskikh Soedinenii, No. 6, pp. 837–840, June, 1985.

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Kuznetsov, A.I., Kosmakov, V.A. & Unkovskii, B.V. Heteroadamantanes and their derivatives. 4. Synthesis of 1,3,5-triazaadamantane. Chem Heterocycl Compd 21, 697–700 (1985). https://doi.org/10.1007/BF00515076

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  • DOI: https://doi.org/10.1007/BF00515076

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