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Chemistry of Heterocyclic Compounds

, Volume 15, Issue 12, pp 1296–1298 | Cite as

Substituted dienic 1,3-dioxolan-2-ones and bis(1,3-dioxolan-2-ones)

  • K. A. Volkova
  • A. N. Nikol'skaya
  • E. P. Levanova
  • A. N. Volkov
  • B. A. Trofimov
Article
  • 31 Downloads

Abstract

Alkylthio-substituted dienic 1,3-dioxolan-2-ones and bis(4,4-diorganyl-5-methyli-dene-1,3-dioxolan-2-ones) were obtained in high yields by the reaction of 2-methyl-6-alkylthio-5-hexen-3-yn-2-ols and tertiary diacetylenic glycols with carbon dioxide under pressure in the presence of catalytic amounts of triethylamine and monovalent copper salts.

Keywords

Copper Dioxide Carbon Dioxide Organic Chemistry Glycol 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    P. Dimroth, E. Schefczik, and H. Pasedach, West German Patent No. 1145632 (1963); Chem. Abstr., 59, 6412a (1963).Google Scholar
  2. 2.
    A. N. Nikol'skaya, E. P. Levanova, A. N. Volkov, R. N. Kudyakova, and K. A. Volkova, Izv. Akad. Nauk SSSR, Ser. Khim., No. 6, 1403 (1977).Google Scholar
  3. 3.
    E. B. Oleinikova, A. N. Volkov, and Yu. M. Skvortsov, Zh. Prikl. Khim., 50, 225 (1977).Google Scholar
  4. 4.
    L. Bellamy, The Infrared Spectra of Complex Molecules, 3rd ed., Halsted Press (1975).Google Scholar

Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • K. A. Volkova
    • 1
  • A. N. Nikol'skaya
    • 1
  • E. P. Levanova
    • 1
  • A. N. Volkov
    • 1
  • B. A. Trofimov
    • 1
  1. 1.Irkutsk Institute of Organic Chemistry, Siberian BranchAcademy of Sciences of the USSRIrkutsk

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