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Reactivities of heterocyclic compounds in nitration. 7. Experimental and theoretical study of the reactivities of pyridines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The relationship between the rates of nitration of pyridines and the calculated [by the CNDO/2 (complete neglect of differential overlap) method] indexes of aromatic electrophilic substitution was investigated. The possibility of the use of two-center components of the localization energies for the theoretical description of the reactivities of pyridines in nitration is demonstrated. The rates of nitration of a number of previously uninvestigated pyridines are predicted.

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Authors and Affiliations

  1. S. M. Kirov Kazan Institute of Chemical Technology, 420015, Kazan

    G. P. Sharnin, I. Sh. Saifullin, I. F. Falyakhov, F. G. Khairutdinov, T. G. Bol'shakova & V. V. Zverev

  2. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, 420062, Kazan

    G. P. Sharnin, I. Sh. Saifullin, I. F. Falyakhov, F. G. Khairutdinov, T. G. Bol'shakova & V. V. Zverev

Authors
  1. G. P. Sharnin
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  2. I. Sh. Saifullin
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  3. I. F. Falyakhov
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  4. F. G. Khairutdinov
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  5. T. G. Bol'shakova
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  6. V. V. Zverev
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Additional information

See [1] for Communication 6.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 639–642, May, 1983.

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Sharnin, G.P., Saifullin, I.S., Falyakhov, I.F. et al. Reactivities of heterocyclic compounds in nitration. 7. Experimental and theoretical study of the reactivities of pyridines. Chem Heterocycl Compd 19, 514–517 (1983). https://doi.org/10.1007/BF00514461

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  • DOI: https://doi.org/10.1007/BF00514461

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