Abstract
9-Phenylethynyl-4-azafluoren-9-ol, which was obtained from 4-azafluorenone and phenylethynylmagnesium iodide, was used in syntheses of isomeric 9-phenacylidene-4-azafluorenes and spiro compounds with indene, indan, and pyrazoline fragments. It is assumed that the conversion of 9-phenacylidene derivatives to spiro compounds takes place via intramolecular substitution.
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O. Kruber and L. Rappen, Chem. Ber., 81, 483 (1948).
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 510–513, April, 1984.
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Prostakov, N.S., Makuli, M., Mikhailova, N.M. et al. Preparation of 9-phenylethynyl-4-azafluoren-9-ol and 9-phenacylidene-4-azafluorene and their conversion to spiro compounds. Chem Heterocycl Compd 20, 413–416 (1984). https://doi.org/10.1007/BF00513858
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DOI: https://doi.org/10.1007/BF00513858