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Chemistry of Heterocyclic Compounds

, Volume 20, Issue 8, pp 846–849 | Cite as

Synthesis and properties of vinyl ethers of 3,4-di(hydroxymethyl)-1,2,5-oxadiazole

  • B. A. Trofimov
  • N. A. Nedolya
  • M. Ya. Khil'ko
  • V. B. Modonov
  • É. I. Kositsyna
  • V. M. Bzhezovskii
  • G. A. Gareev
Article

Abstract

The direct vinylation of 3,4-di(hydroxymethyl)-1,2,5-oxadiazole by acetylene was accomplished for the first time; its mono- and divinyl ethers were synthesized in the presence of cadmium acetate. The physicochemical and spectral properties and conformational structure of the synthesized compounds were studied. It was shown that the s-trans-trans-conformation is the most profitable for the divinyl ether of 3,4-di(hydroxymethyl)-1,2,5-oxadiazole.

Keywords

Acetate Ether Cadmium Organic Chemistry Vinyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • B. A. Trofimov
    • 1
  • N. A. Nedolya
    • 1
  • M. Ya. Khil'ko
    • 1
  • V. B. Modonov
    • 1
  • É. I. Kositsyna
    • 1
  • V. M. Bzhezovskii
    • 1
  • G. A. Gareev
    • 1
  1. 1.Irkutsk Institute of Organic Chemistry, Siberian BranchAcademy of Sciences of the USSRIrkutsk

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