Chemistry of Heterocyclic Compounds

, Volume 18, Issue 2, pp 138–140 | Cite as

[3,3]-Sigmatropic rearrangement of chloro-substituted allyl thienyl sulfides

  • S. M. Panov
  • A. V. Anisimov
  • E. A. Viktorova
Article

Abstract

The kinetics of the rearrangement of allyl 5-chloro-2-thienyl sulfide and β-chloroallyl 2-thienyl sulfide to, respectively, 5-chloro-3-allyl-2-thiophenethiol and 3-(β-chloroallyl)-2-thiophenethiol were investigated. It is shown that an acceptor substituent in the allyl group decreases the reactivity of the sulfide significantly, whereas an acceptor in the heterocyclic ring does not have an appreciable effect on it.

Keywords

Sulfide Organic Chemistry Allyl Appreciable Effect Heterocyclic Ring 

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Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • S. M. Panov
    • 1
  • A. V. Anisimov
    • 1
  • E. A. Viktorova
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityMoscow

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