Investigation of the kinetics of the nitration of thiophene derivatives
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- Freidlin, G.N., Glushkova, A.A. & Solop, K.A. Chem Heterocycl Compd (1982) 18: 127. doi:10.1007/BF00512952
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The kinetics of the nitration of thiophene derivatives with nitric acid in acetic anhydride were investigated. The nitration of 2-substituted thiophenes is a second-order reaction. The rate constants and activation parameters of the reaction were calculated. The possibility of the use of the Hanmett and Yukawa-Tsuno equations for this reaction series is demonstrated. An isokinetic dependence is observed.