Chemistry of Heterocyclic Compounds

, Volume 18, Issue 2, pp 127–130 | Cite as

Investigation of the kinetics of the nitration of thiophene derivatives

  • G. N. Freidlin
  • A. A. Glushkova
  • K. A. Solop


The kinetics of the nitration of thiophene derivatives with nitric acid in acetic anhydride were investigated. The nitration of 2-substituted thiophenes is a second-order reaction. The rate constants and activation parameters of the reaction were calculated. The possibility of the use of the Hanmett and Yukawa-Tsuno equations for this reaction series is demonstrated. An isokinetic dependence is observed.


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Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • G. N. Freidlin
    • 1
  • A. A. Glushkova
    • 1
  • K. A. Solop
    • 1
  1. 1.All-Union Scientific-Research and Design Institute of MonomersTula

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