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Application of electrochemical methods to iodatometric titrations

Part II Titration of HgI, SCN−, SbIII and TlI

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Summary

The application of biamperometry and bipotentiometry to the titration of HgI, SCN−, SbIII and TlI with iodate has been investigated, Probable errors range from 0.16% for SbIII to 0.96% for SCN−, for quantities between 10−5 and 2×10−4moles.

Zusammenfassung

Es wird über die Verwendung von biamperometrischen und bipotentiometrischen Methoden bei jodatometrischen Titrationen von HgI, SCN−, SbIII und TlI berichtet.

Die wahrscheinliche Abweichung des Verfahrens beträgt 0,16% (SbIII) bis 0,96% (SCN−) für Mengen von 10−5 bis 2 · 10−4 Mol.

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Authors and Affiliations

  1. Istituto di Chimica Analitica dell'Universitá di Padova, Italien

    Riccardo Freddi, Giuseppe Giorgio Bombi & Mario Fiorani

Authors
  1. Riccardo Freddi
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  2. Giuseppe Giorgio Bombi
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  3. Mario Fiorani
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This work was supported by the Italian Council of Research (Consiglio Nazionale delle Ricerche).

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Freddi, R., Bombi, G.G. & Fiorani, M. Application of electrochemical methods to iodatometric titrations. Z. Anal. Chem. 222, 369–381 (1966). https://doi.org/10.1007/BF00511262

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  • DOI: https://doi.org/10.1007/BF00511262

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