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Chemistry of Heterocyclic Compounds

, Volume 7, Issue 9, pp 1180–1182 | Cite as

Investigation of nitrogen-containing heterocyclic free radicals

XIV.Rate of dissociation of diaryl-β-naphthylimidazolyl radicals
  • B. S. Tanaseichuk
  • A. A. Bardina
  • A. A. Khomenko
Article
  • 40 Downloads

Abstract

Dimers of 4(5)-phenyl-5(4)-β-naphthyl-2-phenyl-substituted imidazolyl radicals were synthesized in order to study the effect of a β-naphthyl group on the stability of triaryl-imidazolyl radicals, and the rate constants and energies of activation for dissociation of the dimers were determined. The presence of a β-naphthyl group in the bistriarylimid-azolyl molecule facilitates its dissociation into radicals as compared with bistriphenyl-imidazolyl.

Keywords

Organic Chemistry Free Radical Imidazolyl 
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Literature cited

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Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • B. S. Tanaseichuk
    • 1
  • A. A. Bardina
    • 1
  • A. A. Khomenko
    • 1
  1. 1.N. P. Ogarev Mordovskii State UniversitySaransk

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