Skip to main content
SpringerLink
Log in

Investigation of nitrogen-containing heterocyclic free radicals

XIV.Rate of dissociation of diaryl-β-naphthylimidazolyl radicals

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Dimers of 4(5)-phenyl-5(4)-β-naphthyl-2-phenyl-substituted imidazolyl radicals were synthesized in order to study the effect of a β-naphthyl group on the stability of triaryl-imidazolyl radicals, and the rate constants and energies of activation for dissociation of the dimers were determined. The presence of a β-naphthyl group in the bistriarylimid-azolyl molecule facilitates its dissociation into radicals as compared with bistriphenyl-imidazolyl.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. B. S. Tanaseichuk, A. A. Bardina, and V. A. Maksakov, Zh. Organ. Khim., 7, 1508 (1971).

    Google Scholar 

  2. A. A. Bardina, B. S. Tanaseichuk, and A. A. Khomenko, Zh. Organ. Khim., 7, 1267 (1971).

    Google Scholar 

  3. T. S. Tanaseichuk, K. V. Stanovkina, A. N. Sunin, and L. G. Rezepova, Zh. Organ. Khim., 5, 2054 (1969).

    Google Scholar 

  4. B. S. Tanaseichuk and L. G. Rezepova, Zh. Organ. Khim., 6, 1065 (1970).

    Google Scholar 

  5. D. M. White and J. Sonnenberg, J. Am. Chem. Soc., 88, 3825 (1966).

    Google Scholar 

  6. S. Goldschmidt and K. Renn, Ber., 55, 628 (1922).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. P. Ogarev Mordovskii State University, Saransk

    B. S. Tanaseichuk, A. A. Bardina & A. A. Khomenko

Authors
  1. B. S. Tanaseichuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Bardina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. A. Khomenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

See [1] for communication XIII.

Translated from Khimiya Geterotsiklicheskikh Soedinnii, No. 9, pp. 1255–1257, September, 1971.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tanaseichuk, B.S., Bardina, A.A. & Khomenko, A.A. Investigation of nitrogen-containing heterocyclic free radicals. Chem Heterocycl Compd 7, 1180–1182 (1971). https://doi.org/10.1007/BF00510032

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00510032

Keywords

Search

Navigation