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Study of the reaction between 2-imino-5-(chloromethyl) oxazolidine-1, 3 and metallic sodium or disodium acetylide

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of 2-imino-5-(chloromethyl) oxazolidine-1, 3 with metallic sodium or disodium acetylide is investigated. Conditions are found for obtaining 1, 2-bis(2-iminooxazolil-5′-yl)-ethane and 1, 4-bis(2′-iminooxazolid-5′-yl) but-2-yne, respectively saponified to 1, 6-diaminohexane-2, 5-diol and 1, 8-diaminooct-4-yne-2, 7-diol. It is intended to use these compounds as monomers for preparing polyamide resins.

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References

  1. K. A. Kocheshkov and T. V. Talalaev, Synthetic Methods for Lithium, Sodium, Potassium, etc Organometallic Compounds [in Russian], Izd-vo AN SSR, 220, 1949.

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Matveev, I.S., Politun, N.N. Study of the reaction between 2-imino-5-(chloromethyl) oxazolidine-1, 3 and metallic sodium or disodium acetylide. Chem Heterocycl Compd 2, 375–376 (1967). https://doi.org/10.1007/BF00509423

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  • DOI: https://doi.org/10.1007/BF00509423

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