Skip to main content
Log in

Thermal conductivity of methane

  • Published:
International Journal of Thermophysics Aims and scope Submit manuscript

Abstract

This paper reports thermal conductivity data for methane measured in the temperature range 120–400 K and pressure range 25–700 bar with a maximum uncertainty of ± 1%. A simple correlation of these data accurate to within about 3% is obtained and used to prepare a table of recommended values.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Abbreviations

a k ,b ij ,b k :

Parameters of the regression model, k= 0 to n; i =0 to m; j =0 to n

P :

Pressure (MPa or bar)

Q kl :

Heat flux per unit length (mW · m−1)

t :

time (s)

T :

Temperature (K)

T cr :

Critical temperature (K)

T r :

reduced temperature (= T/T cr)

ΔT w :

Temperature rise of wire between times t 1 and t 2 (deg K)

ΔT * :

Reduced temperature difference (TśT cr)/T cr

λ:

Thermal conductivity (mW · m−1 · K−1)

λ1 :

Thermal conductivity at 1 bar (mW · m−1 · K−1)

λbg :

Background thermal conductivity (mW · m−1 · K−1)

Δλcr :

Anomalous thermal conductivity (mW · m−1 · K−1)

Δλe :

Excess thermal conductivity (mW · m−1 · K−1)

ρ :

Density (g · cm−3)

ρ cr :

Critical density (g · cm−3)

ρ r :

Reduced density (= ρ/ρ cr)

Δρ * :

Reduced density difference (ρ−ρ cr )/ρ cr

References

  1. E. S. Borovik, A. Manveev, and Y. E. Pania, Z. Tekh. Fiz. 10:988 (1940).

    Google Scholar 

  2. H. L. Johnston and E. R. J. Grilly, J. Chem. Phys. 14:233 (1946).

    Google Scholar 

  3. F. G. Keyes, Trans. ASME 76:809 (1954).

    Google Scholar 

  4. V. H. Geier and K. Schafer, Allg. Warmetechnik. 10:70 (1961).

    Google Scholar 

  5. L. Ikenberry and S. A. Rice, J. Chem. Phys. 39:1561 (1963).

    Google Scholar 

  6. I. F. Golubev, Teploenergetika 12:78 (1963).

    Google Scholar 

  7. L. T. Carmichael, H. H. Reamer, and B. H. Sage, J. Chem. Eng. Data 11:52 (1966).

    Google Scholar 

  8. D. Misic and G. Thodos, Physica 32:885 (1966).

    Google Scholar 

  9. B. H. Rosenbaum and G. Thodos, Physica 37:442 (1967).

    Google Scholar 

  10. B. Le Neindre, R. Tufeu, P. Bury, P. Johannin, and B. Vodar, Laboratoire des Hautes Pressions-CNRS-1, Place-A, Briand-Bellevue, France (1969).

    Google Scholar 

  11. V. P. Sikolova and I. F. Golubev, Teploenergetica 14:91 (1967).

    Google Scholar 

  12. M. H. Gonzales, T. K. Subramaniam, R. L. Rao, and A. L. Lee, Inst. Gas Tech., Session No. 5, paper 21, Chicago (1968).

  13. R. C. Prasad and J. E. S. Venart, to be published.

  14. E. R. M. Van der Held and F. G. Van Drunen, Physica 15:865 (1949).

    Google Scholar 

  15. N. Mani, Precise Determination of the Thermal Conductivity of Fluids Using Absolute Transient Hot-Wire Technique, Ph.D. Dissertation, University of Calgary, Canada (1971).

    Google Scholar 

  16. R. D. Goodwin, Nat. Bur. Stand. (U.S.) Tech. Note 653 (1954).

  17. J. V. Sengers, R. S. Basu, and J. M. H. L. Sengers, NASA Contractor Report 3424 (1981).

  18. R. C. Prasad and J. E. S. Venart, to be published.

  19. W. T. Kierkus, N. Mani, and J. E. S. Venart, Can. J. Phys. 51:1182 (1973).

    Google Scholar 

  20. A. Eucken, Z. Physik, 14:342 (1913), as cited in Ref. 22.

    Google Scholar 

  21. S. Weber, Ann. Physik 54:437 (1917).

    Google Scholar 

  22. W. B. Mann and B. G. Dickins, Proc. Roy. Soc. London A 134:77 (1931).

    Google Scholar 

  23. N. V. Tsederberg, Thermal Conductivity of Gases and Liquids (MIT Press, Cambridge, Massachusetts, 1965).

    Google Scholar 

  24. B. Le Neindre, R. Tufeu, P. Bury, and J. V. Sengers, Ber. Bunsen ges. Phys. Chem. 77:262 (1973).

    Google Scholar 

  25. H. J. M. Hanley, J. V. Sengers, and J. F. Ely, in Thermal Conductivity 14, P. G. Klemens and T. K. Chu, eds. (New York, 1976), p. 383.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Prasad, R.C., Mani, N. & Venart, J.E.S. Thermal conductivity of methane. Int J Thermophys 5, 265–279 (1984). https://doi.org/10.1007/BF00507836

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00507836

Key words

Navigation