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Kinetics of N-oxidation of compounds of the quinoline series and isomeric benzoquinolines by perbenzoic acid in chloroform and aqueous dioxane

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Abstract

The kinetics of the N-oxidation with perbenzoic acid of 15 derivatives of quinoline and benzoquinoline in chloroform and 19 compounds in 50% aqueous dioxane at 20, 25, 30, and 35 °C were subjected to a comparative study. The rate constants, parameters of the Arrhenius equation, and the activation energies for the N-oxidation of the indicated monoazines were determined. A scale of the reactivities of derivatives of the quinoline series and benzoquinolines was calculated within the framework of general perturbation theory.

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Authors and Affiliations

  1. K. L. Khetagurov North Ossetian State Pedagogical Institute, 362000, Ordzhonikidze

    R. E. Lokhov

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  1. R. E. Lokhov
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 89–94, January, 1981.

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Lokhov, R.E. Kinetics of N-oxidation of compounds of the quinoline series and isomeric benzoquinolines by perbenzoic acid in chloroform and aqueous dioxane. Chem Heterocycl Compd 17, 72–76 (1981). https://doi.org/10.1007/BF00507096

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  • DOI: https://doi.org/10.1007/BF00507096

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