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Rearrangements in the haloalkoxy(thio,amino)-sym-triazine series. 10. Synthesis and rearrangement of 2-dimethylamino-4-(2-acylhydrazino)-6,7-dihydrooxazolo[3,2-a]-sym-triazines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

2-Dimethylamino-4-(2-acetylhydrazino)- and 4-(2-benzoyl)hydrazino-6,7-dihydrooxazolo[3,2-a]-sym-triazines were synthesized. It was established that when these compounds are heated, they undergo rearrangement to the corresponding 2-dimethylamino-6,7-dihydroimidazo[2,1-a]-sym-triazines. Deacylation of the latter gives the N-amino derivative.

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  1. V. V. Dovlatyan, N. Kh. Khachatryan, and T. A. Gomktsyan, Khim. Geterotsikl. Soedin., No. 8, 1125 (1981).

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  2. V. V. Dovlatyan, A. V. Dovlatyan, K. A. Eliazyan, and R. G. Mirzoyan, Khim. Geterotsikl. Soedin., No. 10, 1420 (1977).

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, 1689–1692, December, 1981

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Dovlatyan, V.V., Khachatryan, N.K., Gomktsyan, T.A. et al. Rearrangements in the haloalkoxy(thio,amino)-sym-triazine series. 10. Synthesis and rearrangement of 2-dimethylamino-4-(2-acylhydrazino)-6,7-dihydrooxazolo[3,2-a]-sym-triazines. Chem Heterocycl Compd 17, 1244–1247 (1981). https://doi.org/10.1007/BF00507004

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  • DOI: https://doi.org/10.1007/BF00507004

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