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Reactions involving shifting of the double bond in cyclic ethers

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

4-Methylenetetrahydropyran undergoes isomerization to 4-methyl-5,6-dihydropyran in the presence of sodium on aluminum oxide. Both pyrans are converted to a vinyl ether, viz., 4-methyl-2,3-dihydropyran, under the influence of iron pentacarbonyl.

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Literature cited

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Authors and Affiliations

  1. Bashkir State University, 450074, Ufa

    U. G. Ibatullin, T. F. Petrushina, A. A. Akhmadeeva & M. G. Safarov

Authors
  1. U. G. Ibatullin
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  2. T. F. Petrushina
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  3. A. A. Akhmadeeva
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  4. M. G. Safarov
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 318–320, March, 1985.

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Ibatullin, U.G., Petrushina, T.F., Akhmadeeva, A.A. et al. Reactions involving shifting of the double bond in cyclic ethers. Chem Heterocycl Compd 21, 262–264 (1985). https://doi.org/10.1007/BF00506660

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  • DOI: https://doi.org/10.1007/BF00506660

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