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Chemistry of Heterocyclic Compounds

, Volume 18, Issue 12, pp 1290–1294 | Cite as

Cyanoethylation of azafluorenes and syntheses of alcohols containing an azafluorene fragment

  • N. S. Prostakov
  • B. Kh. Sisimbina
  • S. A. Soldatova
  • V. P. Shalimov
  • K. G. Montenegro
  • N. I. Leonova
  • L. A. Murugova
Article
  • 30 Downloads

Abstract

Isomeric (with respect to the position of the nitrogen atom) azafluorenes were cyanoethylated. The resulting 9,9-bis(β-cyanoethyl) derivatives were converted to the corresponding dibasic acids and their diesters. The latter were subjected to the Dieckmann reaction to obtain spiro compounds with azafluorene and cyclohexene fragments. The analogous spirans with 1,3-dioxalane and 1,3-dioxane rings were obtained from 3-methyl-2-azafluorenone.

Keywords

Nitrogen Alcohol Organic Chemistry Nitrogen Atom Cyclohexene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • N. S. Prostakov
    • 1
  • B. Kh. Sisimbina
    • 1
  • S. A. Soldatova
    • 1
  • V. P. Shalimov
    • 1
  • K. G. Montenegro
    • 1
  • N. I. Leonova
    • 1
  • L. A. Murugova
    • 1
  1. 1.Patrice Lumumba People's Friendship UniversityMoscow

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