Chemistry of Heterocyclic Compounds

, Volume 19, Issue 2, pp 203–206 | Cite as

Chemistry of heterocycylic N-oxides and related compounds. 12. Diphenylhydroxymethylation of quinoline N-oxide with benzophenone ketyls and dianions

  • A. S. Kurbatova
  • Yu. V. Kurbatov
  • V. K. Yu
Article

Abstract

Diphenylhydroxymethylation of the pyridine ring to give diphenyl(2-quinolyl)carfabinol or its N-oxide occurs in the reaction of quinoline N-oxide with benzophenone ketyls and dianions. The best results are obtained when the lithium ketyl is used. A reduction product, viz., quinoline, is formed simultaneously in all of the reactions.

Keywords

Lithium Organic Chemistry Pyridine Quinoline Related Compound 

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Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • A. S. Kurbatova
    • 1
  • Yu. V. Kurbatov
    • 1
  • V. K. Yu
    • 1
  1. 1.A. Navoi Samarkand State UniversitySamarkand

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