Abstract
A number of derivatives of mercaptomono- and dinitroimidazoles were synthesized by the action of potassium sulfide on the corresponding halonitroimidazoles. Mono- and dipotassium salts of mercaptonitroimidazoles were obtained. It was established that the monopotassium salts of mercaptomono- and dinitroimidazoles react with 2,4,6-trinitrochlorobenzene to give picrylmercapto derivatives, dipotassium salts of mononitromercaptoimidazoles give, depending on the ratio of the components, picrylmercaptonitroimidazoles or S.N-dipicrylmercaptonitroimidazoles, and dipotassium salts of mercaptodinitroimidazole give only picrylmercaptonitroimidazoles.
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V. K. Bhagwat and F. L. Pyman, J. Chem. Soc., 127, 1832 (1925).
L. L. Bennett and H. T. Baker, J. Am. Chem. Soc., 79, 2188 (1957).
M. H. Fisher, W. H. Nicholson, and R. S. Stuart, Can. J. Chem., 39, 501, 781 (1961).
P. M. Kochergin, Khim. Geterotstkl. Soedin., No. 5, 749 (1966).
V. Ipatieff, H. Pines, and B. Friedman, J. Am. Chem. Soc., 60, 2495 (1938).
S. S. Novikov, L. I. Khmel'nitskii, O. V. Lebedev, L. V. Epishina, and V. V. Sevost'yanova, Khim. Geterotsikl. Soedin., No. 5, 664 (1970).
G. P. Sharnin, V. V. Nurgatin, and B. I. Buzykin, Zh. Org. Khim., 3, 1245 (1967).
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 812–816, June, 1982.
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Nurgatin, V.V., Sharnin, G.P., Nurgatina, R.B. et al. Synthesis of mercaptonitroimidazoles and their reaction with 2,4,6-trinitrochlorobenzene. Chem Heterocycl Compd 18, 616–619 (1982). https://doi.org/10.1007/BF00506156
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DOI: https://doi.org/10.1007/BF00506156