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Chemistry of Heterocyclic Compounds

, Volume 18, Issue 6, pp 566–568 | Cite as

Synthesis of thiirane oximes from 3,4-dibromo-3-methyl-2-butanone oxime

  • V. P. Tashchi
  • T. I. Rukasov
  • Yu. G. Orlova
  • Yu. A. Putsykin
  • Yu. A. Baskakov
Article

Abstract

2-(α-Oximinoethyl)-2-methylthiirane was obtained by the reaction of 3,4-dibromo-3-methyl-2-butanone oxime with sodium sulfide. At the same time, the O-carbamoyl derivative of the α,β-dibromo oxime was converted to the corresponding substituted α,β-unsaturated oxime under the same conditions. Thiirane oxime, like its O-carbamoyl derivative, underwent the desulfuration that is characteristic for thirranes under the influence of tributylphosphine.

Keywords

Sodium Sulfide Organic Chemistry Oxime Sodium Sulfide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • V. P. Tashchi
    • 1
  • T. I. Rukasov
    • 1
  • Yu. G. Orlova
    • 1
  • Yu. A. Putsykin
    • 1
  • Yu. A. Baskakov
    • 1
  1. 1.All-Union Scientific-Research Institute of Chemical Agents for the Protection of PlantsMoscow

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