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Sigma complexes in the pyrimidine series. 6. Reaction of 5-nitro-2-methoxy- and 5-nitro-4,6-dimethoxypyrimidines with the acetylacetone carbanion

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Depending on the reaction conditions, the reaction of 5-nitro-2-methoxy- and 5-nitro-4,6-dimethoxypyrimidines with the acetylacetone carbanion gives potassium salts of 5-nitrodiacetylmethylenepyrimidines or, as a result of recyclization of the pyrimidine ring, 5-nitro-2-hydroxyacetophenone.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, 252660, Kiev

    G. Ya. Remennikov, A. A. Kisilenko & V. M. Cherkasov

Authors
  1. G. Ya. Remennikov
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  2. A. A. Kisilenko
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  3. V. M. Cherkasov
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Additional information

See [1] for communication 5.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1393–1397, October, 1983.

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Remennikov, G.Y., Kisilenko, A.A. & Cherkasov, V.M. Sigma complexes in the pyrimidine series. 6. Reaction of 5-nitro-2-methoxy- and 5-nitro-4,6-dimethoxypyrimidines with the acetylacetone carbanion. Chem Heterocycl Compd 19, 1109–1113 (1983). https://doi.org/10.1007/BF00505768

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  • DOI: https://doi.org/10.1007/BF00505768

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