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σ,π Complexing capacities of heteroaromatic compounds (review)

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The results of experimental studies and quantum-chemical calculations of pyrrole, methylpyridines, and azoles obtained in recent years make it possible to formulate the conditions for the manifestation of π-complexing capacities by π-deficient compounds and compounds of a similar nature, viz., blocking of the σ-donor center in the case of ortho substitution by alkyl groups and primary H or v bonding.

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Authors and Affiliations

  1. M. A. Suslov Rostov State University, 344006, Rostov-on-Don

    A. P. Sadimenko, A. D. Garnovskii, V. N. Sheinker & O. A. Osipov

  2. Rostov-on-Don Institute of Agricultural, Rostov Pedagogical Institute, Machine Building, USSR

    A. P. Sadimenko, A. D. Garnovskii, V. N. Sheinker & O. A. Osipov

Authors
  1. A. P. Sadimenko
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  2. A. D. Garnovskii
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  3. V. N. Sheinker
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  4. O. A. Osipov
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Additional information

Paper presented at the 12th Mendeleev Conference on General and Applied Chemistry [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1299–1310, October, 1983.

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Sadimenko, A.P., Garnovskii, A.D., Sheinker, V.N. et al. σ,π Complexing capacities of heteroaromatic compounds (review). Chem Heterocycl Compd 19, 1031–1041 (1983). https://doi.org/10.1007/BF00505745

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  • DOI: https://doi.org/10.1007/BF00505745

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