Chemistry of Heterocyclic Compounds

, Volume 17, Issue 5, pp 490–497 | Cite as

Synthesis and three-dimensional structure of 2-arylidene-3-oxoquinuclidine oximes

  • T. Ya. Filipenko
  • O. I. Gorbyleva
  • K. F. Turchin
  • O. S. Anisimova
  • E. M. Peresleni
  • E. E. Mikhlina
  • Yu. N. Sheinker
  • L. N. Yakhontov
Article
  • 25 Downloads

Abstract

2-Arylidene-3-oxoquinuclidine oximes were obtained from the products of condensation of 3-oxoquinuclidine with aromatic aldehydes. It is shown that three of the four theoretically possible isomers (isomerism involving the C=C and C=N bonds) are formed; their thermal stability was studied. The structures of the isomeric oximes was established on the basis of data from the 1H and 13C NMR spectra and were confirmed by data from chromatographic mass spectrometry and the UV and IR spectra.

Keywords

Mass Spectrometry Organic Chemistry Thermal Stability Aldehyde Oxime 

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Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • T. Ya. Filipenko
    • 1
  • O. I. Gorbyleva
    • 1
  • K. F. Turchin
    • 1
  • O. S. Anisimova
    • 1
  • E. M. Peresleni
    • 1
  • E. E. Mikhlina
    • 1
  • Yu. N. Sheinker
    • 1
  • L. N. Yakhontov
    • 1
  1. 1.S. Ordzhonikidze All-Union Scientific-Research Institute of Pharmaceutical ChemistryMoscow

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