Abstract
Condensation of acetophenones with acetic anhydride in the presence of boron trifluoride etherate has given some 2-methyl -4,6-diarylpyrilium tetrafluoroborates. The optimum conditions for the synthesis of 2-methyl-substituted pyrilium salts have been established.
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A. T. Balaban, W. Schroth, and G. Fischer, Advances in Heterocyclic Chemistry, Vol. 10, Academic Press, New York-London (1969), p. 325.
I. I. Boiko, T. A. Markina, T. N. Boiko, N. A. Pochkailo, A. G. Darmenko, and D. G. Kozhich, Abstr. All-Union Conf., Molecular Luminesecence and Its Applications [in Russian], Khar'kov (1982), p. 35.
G. N. Dorofeenko, E. N. Sadekova, and E. V. Kuznetsov, The Preparative Chemistry of Pyrilium Compounds [in Russian], Rostov-on-Don, Izd. Rost. Univ. (1972).
Y. A. Durden and D. G. Crosby, J. Org. Chem., 30, 1684 (1965).
L. G. S. Brocker, D. W. Heseltine, and D. S. Daniel, US Pat. No. 3567438; Chem. Abstr., 73, 30661 (1970).
A. M. Duffield, C. Djerassi, and A. T. Balaban, Org. Mass Spectrom., 5, 87 (1971).
J. Hvistendahl and P. Gyorosi, Org. Mass Spectrom., 9, 80 (1974).
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Translated from Khimiya Geterotsiklicheskikh Soedenii, No. 2, pp. 173–176, February, 1985.
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Markina, T.A., Boiko, N.N. Synthesis of 2-methyl-4,6-diarylpyrilium tetrafluoroborates. Chem Heterocycl Compd 21, 138–141 (1985). https://doi.org/10.1007/BF00504194
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DOI: https://doi.org/10.1007/BF00504194