Abstract
Viscosity coefficient measurements made with an estimated accuracy of ±2% using a self-centering falling body viscometer are reported for benzene, perdeuterobenzene, hexafluorobenzene and an equimolar mixture of benzene + hexafluorobenzene at 25, 50, 75 and 100°C at pressures up to the freezing pressure. The data for each liquid at different temperatures and pressures are correlated very satisfactorily by a graphical method based on plots of 9.118×107 ηV 2/3/(MRT)1/2 versus logV, and are reproduced to within the experimental uncertainty by a free-volume form of equation. Application of the empirical Grunberg and Nissan equation to the mixture viscosity coefficient data shows that the characteristic constant G is practically temperature- and pressure-independent for this system.
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Dymond, J.H., Robertson, J. & Isdale, J.D. Transport properties of nonelectrolyte liquid mixtures—IV. Viscosity coefficients for benzene, perdeuterobenzene, hexafluorobenzene, and an equimolar mixture of benzene + hexafluorobenzene from 25 to 100°c at pressures up to the freezing pressure. Int J Thermophys 2, 223–236 (1981). https://doi.org/10.1007/BF00504186
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DOI: https://doi.org/10.1007/BF00504186