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Chemistry of Heterocyclic Compounds

, Volume 20, Issue 10, pp 1099–1101 | Cite as

Heteroatomic derivatives of aziridine. 14. Reactions of 1-(carbomethoxyethyl)-, 1-[1,2-bis(carbethoxy)ethyl]-, and 1-[1,2-bis(carbomethoxy)vinyl]aziridine with thiols, 1,2-ethanedithiol, and thiolcarboxylic acids

  • M. G. Voronkov
  • V. I. Knutov
  • M. K. Butin
Article
  • 43 Downloads

Abstract

The reactions of 1-(carbomethoxyethyl)-, 1-[1,2-bis(carbethoxy)-ethyl]-, and 1-[1,2-bis(carbomethoxy)vinyl]aziridine with thiols and thiolcarboxylic acids produce the corresponding sulfides and esters of S-substituted N-(2-mercaptoethyl) amino acids. The reaction of 1-[1,2-bis(carbethoxy)ethyl]aziridine with 1,2-ethane-dithiol results in the formation of {1,8-bis[1,2-bis(carbethoxy)-ethyl]amino}-3,6-dithiaoctane. Cyclization of the latter by condensation with phthaloyl chloride gives 9,10-benzo-8,11-dioxo-1,4-dithia-7,12-bis[1,2-bis(carbethoxy)ethyl]-7,12-diazacyclotetradec-9-ene.

Keywords

Chloride Ester Ethyl Sulfide Organic Chemistry 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • M. G. Voronkov
    • 1
  • V. I. Knutov
    • 1
  • M. K. Butin
    • 1
  1. 1.Irkutsk Institute of Organic ChemistryAcademy of Sciences of the USSR, Siberian BranchIrkutsk

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