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Synthesis and electrophilic substitution reactions of 2-aryl-3,4-bis(carbomethoxy)furans

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The thermal decomposition of the products of hydrogenation of the adducts obtained from arylfurans and dimethyl acetylenedicarboxylate leads to the formation of 2-aryl-3,4-bis(carbomethoxy)furans. The bromination of these compounds takes place in the 5 position of the furan ring; depending on the concentration of the nitric acid used, nitration leads to the formation of products of nitration in both the furan and the benzene rings.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 453–456, April, 1982.

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Oleinik, A.F., Adamskaya, E.V. & Novitskii, K.Y. Synthesis and electrophilic substitution reactions of 2-aryl-3,4-bis(carbomethoxy)furans. Chem Heterocycl Compd 18, 337–340 (1982). https://doi.org/10.1007/BF00503545

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  • DOI: https://doi.org/10.1007/BF00503545

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