Chemistry of Heterocyclic Compounds

, Volume 17, Issue 10, pp 1032–1034 | Cite as

Synthesis of pyridine and quinoline derivatives of ferrocene from β-chloro-β-ferrocenylacrolein

  • V. V. Krasnikov
  • G. N. Dorofeenko


2-Ferrocenylquinolines that contain a hydroxy or methoxy group in the 7 position were obtained by the reaction of β-chloro-β-ferrocenylacrolein with m-anisidine and with m-aminophenol. The introduction of aniline in this reaction leads to the formation of β-ferrocenyl-β-phenylaminoacrolein anil hydrochloride, which cannot be converted to 2-ferrocenylquinoline. 2,3,6-Trisubstituted pyridines that contain a ferrocenyl substituent in the 6 position were obtained by condensation of β-chloro-β-ferrocenylacrolein with β-dicarbonyl compounds.


Organic Chemistry Pyridine Hydrochloride Aniline Methoxy 
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Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • V. V. Krasnikov
    • 1
  • G. N. Dorofeenko
    • 1
  1. 1.Scientific-Research Institute of Physical and Organic ChemistryRostov State UniversityRostov-on-Don

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