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Chemistry of Heterocyclic Compounds

, Volume 17, Issue 10, pp 1032–1034 | Cite as

Synthesis of pyridine and quinoline derivatives of ferrocene from β-chloro-β-ferrocenylacrolein

  • V. V. Krasnikov
  • G. N. Dorofeenko
Article
  • 55 Downloads

Abstract

2-Ferrocenylquinolines that contain a hydroxy or methoxy group in the 7 position were obtained by the reaction of β-chloro-β-ferrocenylacrolein with m-anisidine and with m-aminophenol. The introduction of aniline in this reaction leads to the formation of β-ferrocenyl-β-phenylaminoacrolein anil hydrochloride, which cannot be converted to 2-ferrocenylquinoline. 2,3,6-Trisubstituted pyridines that contain a ferrocenyl substituent in the 6 position were obtained by condensation of β-chloro-β-ferrocenylacrolein with β-dicarbonyl compounds.

Keywords

Organic Chemistry Pyridine Hydrochloride Aniline Methoxy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • V. V. Krasnikov
    • 1
  • G. N. Dorofeenko
    • 1
  1. 1.Scientific-Research Institute of Physical and Organic ChemistryRostov State UniversityRostov-on-Don

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