Chemistry of Heterocyclic Compounds

, Volume 17, Issue 4, pp 347–349 | Cite as

PMR spectra and structures of 2H,6H-2,6-dimethyl-4-amino-1,3,5-dithiazine and its derivatives

  • V. K. Voronov
  • B. A. Trofimov
  • G. M. Gavrilova
  • S. V. Amosova
  • V. I. Gostevskaya
Article
  • 26 Downloads

Abstract

An analysis of the PMR spectra of 2H, 6H-2, 6-dimethyl-4-amino-1,3,5-dithiazine, its acyl derivatives, and 2H, 3H, 6H-2, 6-dimethyl-4-amino-1,3,5-thiadiazine in various solvents and in the presence of Eu(FOD)3 [tris(1,1,1,2,2,3,3-heptafluoro-7,7-dimettyl-4,6-octanedionato)3 europium] confirms the structure assigned to it and makes it possible to prefer a cis orientation of the methyl substituents in the half-chair conformation.

Keywords

Methyl Europium Organic Chemistry Methyl Substituent Acyl Derivative 

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • V. K. Voronov
    • 1
  • B. A. Trofimov
    • 1
  • G. M. Gavrilova
    • 1
  • S. V. Amosova
    • 1
  • V. I. Gostevskaya
    • 1
  1. 1.Irkutsk Institute of Organic ChemistrySiberian Branch, Academy of Sciences of the USSRIrkutsk

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