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Synthesis of tetraphenylporphins with active groups in the phenyl rings. 1. Preparation of tetrakis(4-aminophenyl)porphin

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Condensation of p-nitrobenzaldehyde with pyrrole in propionic acid with added acetic anhydride gave tetrakis(4-nitrophenyl)porphin (24%), by the reduction of which tetrakis(4-aminophenyl)porphin, which was also obtained by hydrolysis of tetrakis(4-acetamidophenyl)porphin, was synthesized.

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Literature cited

  1. A. S. Semeikin, O. I. Koifman, and B. D. Berezin, Khim. Khim. Tekhnol., 24, 566 (1981).

    Google Scholar 

  2. O. I. Koifman and A. S. Semeikin, in: The Chemistry and Technology of Dyeing and the Synthesis of Dyes and Polymeric Materials [in Russian], Ivanovo. (1979), p. 133.

  3. R. G. Little, J. A. Anton, P. A. Loach, and. J. A. Ibers, J. Heterocycl. Chem., 12, 343 (1975).

    Google Scholar 

  4. J. P. Collman, C. M. Elliott, T. R. Halbert, and B. S. Tovrog, Proc. Natl. Acad. Sci., U.S.A., 74, 18 (1977).

    Google Scholar 

  5. N. Datta-Gupta and T. J. Bardos, J. Heterocycl. Chem., 3, 495 (1966).

    Google Scholar 

  6. A. Treibs and N. Haberle, Liebigs Ann. Chem., 718, 183 (1968).

    Google Scholar 

  7. A. S. Semeikin, O. I. Koifman, and B. D. Berezin, USSR Inventor's Certificate No. 808501; Byull. Izobret., No. 8, 36 (1981).

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1354–1355, October, 1982.

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Semeikin, A.S., Koifman, O.I. & Berezin, B.D. Synthesis of tetraphenylporphins with active groups in the phenyl rings. 1. Preparation of tetrakis(4-aminophenyl)porphin. Chem Heterocycl Compd 18, 1046–1047 (1982). https://doi.org/10.1007/BF00503191

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  • DOI: https://doi.org/10.1007/BF00503191

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