Chemistry of Heterocyclic Compounds

, Volume 11, Issue 4, pp 500–503 | Cite as

Destructive hydrazinolysis of [1,2,4]triazolo[3,4-b]-[1,3,4] thiadiazole derivatives

  • I. Ya. Postovskii
  • A. D. Sinegibskaya
  • E. G. Kovalev
Article

Abstract

The hydrazinolysis of 2-mercapto[1,2,4]triazolino[3,4-b][1,3,4]triadiazole-5-thione and its S-methyl and disulfonyl derivatives leads to opening of the thiadiazole ring during attack by the nucleophile on the bridge carbon atom. A study of the structures of the reaction products and calculations by the Hückel MO and Pariser-Parr-Pople (PPP) method makes it possible to draw a conclusion regarding the mechanism of the hydrazinolysis.

Keywords

Organic Chemistry Carbon Atom Thiadiazole Bridge Carbon Thiadiazole Derivative 

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • I. Ya. Postovskii
    • 1
  • A. D. Sinegibskaya
    • 1
  • E. G. Kovalev
    • 1
  1. 1.S. M. Kirov Urals Polytechnic InstituteSverdlovsk

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