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Spektrometrische Chlorbestimmimg unter Anwendung eines modifizierten Beilsteintests

Spectrometric determination of chlorine by modified Beilstein test

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  • Spectroscopic Methods
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Summary

Chlorinated organic compounds react with the brass-nozzle of the dc-plasma jet. The products generated (of the type CuCl x ) cause an emission signal for copper equivalent to the content of chlorine. An analogous signal can be observed for organic substances containing bromine or iodine; a signal does not appear for fluorinated substances. This modified Beilstein principle may be used for the determination of small amounts of chlorinated organic substances by optical emission spectrometry after pre-separation by gas-chromatography.

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Author notes

  1. Ralph Hebisch

    Present address: Sektion Chemie, Humboldt-Universität zu Berlin, DDR-1040, Berlin

Authors and Affiliations

  1. Technische Hochschule „Carl Schorlemmer“ Leuna-Merseburg, DDR-4200, Merseburg, Deutsche Demokratische Republik

    Klaus Doerffel & Ralph Hebisch

Authors
  1. Klaus Doerffel
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  2. Ralph Hebisch
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Doerffel, K., Hebisch, R. Spektrometrische Chlorbestimmimg unter Anwendung eines modifizierten Beilsteintests. Z. Anal. Chem. 334, 242–245 (1989). https://doi.org/10.1007/BF00497250

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  • DOI: https://doi.org/10.1007/BF00497250

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