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Die selektive invers-voltammetrische Bestimmung des Antimons in salzsauren Lösungen nach Lösungswechsel in einer einfachen Durchflußzelle

The selective inverse-voltammetric determination of antimony in hydrochloric acid solutions after medium exchange in a simple flow-through cell

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Summary

The selective invers-voltammetric determination of antimony in a simple flow-through cell in hydrochloric acid solutions is described. After double medium exchange for post-electrolysis and inverse-voltammetric determination, the determination of antimony is possible in the presence of a large excess of copper, bismuth and other elements. The limit of determination is 0.2–0.3 ppb Sb, the reproducibility 1.5% (10 ppb Sb).

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Authors and Affiliations

  1. Institut für Anorganische Chemie und Analytische Chemie, Johannes-Gutenberg-Universität Mainz, Postfach 3980, D-6500, Mainz 1, Bundesrepublik Deutschland

    Thomas Frank & Rolf Neeb

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  1. Thomas Frank
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  2. Rolf Neeb
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Frank, T., Neeb, R. Die selektive invers-voltammetrische Bestimmung des Antimons in salzsauren Lösungen nach Lösungswechsel in einer einfachen Durchflußzelle. Z. Anal. Chem. 327, 670–673 (1987). https://doi.org/10.1007/BF00489158

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  • DOI: https://doi.org/10.1007/BF00489158

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