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Synthesis of 2-furylcyclopropanes new modification of the kishner synthesis of cyclopropanes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A new one-step modification of the synthesis of cyclopropane-ring-substituted 2-furylcyclopropanes by the Kishner method from α,β-unsaturated ketones of the furan series is proposed. Disubstituted cyclopropanes are obtained in the form of mixtures of the cis and trans isomers, as proved by the PMR and gas-liquid chromatography data.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, 117913, Moscow

    V. A. Zefirova & R. A. Karakhanov

Authors
  1. V. A. Zefirova
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  2. R. A. Karakhanov
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1032–1035, August, 1977.

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Zefirova, V.A., Karakhanov, R.A. Synthesis of 2-furylcyclopropanes new modification of the kishner synthesis of cyclopropanes. Chem Heterocycl Compd 13, 828–831 (1977). https://doi.org/10.1007/BF00488900

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  • DOI: https://doi.org/10.1007/BF00488900

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