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Homolytic liquid-phase reactions of 1,3-dioxacyclanes (review)

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The literature data on the liquid-phase homolytic isomerization, addition, substitution, and oxidation reactions of 1,3-dioxacyclanes are examined. The problems involved in the formation, stabilities, kinetics, and mechanisms of the transformations of free radicals in a series of cyclic acetals are discussed. Possibilities for the application of the homolytic transformations of 1,3-dioxacyclanes in organic synthesis are demonstrated.

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Authors and Affiliations

  1. Ufa Petroleum Institute, 450062, Ufa

    D. L. Rakhmankulov & S. S. Zlot-skii

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  1. D. L. Rakhmankulov
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  2. S. S. Zlot-skii
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1011–1025, August, 1977.

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Rakhmankulov, D.L., Zlot-skii, S.S. Homolytic liquid-phase reactions of 1,3-dioxacyclanes (review). Chem Heterocycl Compd 13, 811–822 (1977). https://doi.org/10.1007/BF00488897

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  • DOI: https://doi.org/10.1007/BF00488897

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