Journal of Sol-Gel Science and Technology

, Volume 5, Issue 2, pp 135–142 | Cite as

Organically substituted titanium alkoxides with unsaturated organic groups

  • Christine Barglik-Chory
  • Ulrich Schubert
Article

Abstract

Modified transition metal alkoxides with polymerizable organic ligands were synthesized which are worthwhile precursors for the development of novel inorganic-organic materials. Titanium tetraisopropoxide was treated with isoeugenol (2-methoxy-4-propenylphenol), itaconic anhydride (methylene succinic anhydride), and 2-acrylamido-2-methyl-propanesulfonic acid, respectively. Isoeugenol forms a chelate complex with titanium via the phenolic OH group and the oxygen of the methoxy substituent. The reaction products of the cyclic itaconic anhydride with titanium alkoxide were two isomers due to different paths of ring opening; the reaction proceeded without the formation of an alcohol. 2-Acrylamido-2-methyl-propanesulfonic acid formed a link to titanium via the SO3 group, and after hydrolysis the sol consisted of rather small particles.

Keywords

precursor chemistry titanium alkoxides polymerizable ligands hybrid materials 

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Copyright information

© Kluwer Academic Publishers 1995

Authors and Affiliations

  • Christine Barglik-Chory
    • 1
  • Ulrich Schubert
    • 2
  1. 1.Fraunhofer-Institut für SilicatforschungWürzburgGermany
  2. 2.Institut für Anorganische Chemie der Technischen Universität WienWienAustria

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