Skip to main content
SpringerLink
Log in

HPLC analysis of Cr, V and Mo using pre- in combination with on-column derivatisation by oxine, bipyridine and H2O2

HPLC-Analyse von Cr, V und Mo unter Verwendung von Vorsäulen- in Kombination mit Säulenderivatisierung durch Oxin, Bipyridin und H2O2

  • Original Papers
  • Chromatographi analyses
  • Published:
Fresenius' Zeitschrift für analytische Chemie Aims and scope Submit manuscript

Summary

The HPLC behaviours of Cr(VI), Mo(VI) and V(V) peroxo complexes in a H2O2-8-hydroxyquinolinebipyridine system were studied by using pre-column in combination with on-column derivatisation. The chromatograms of Cr(VI), Mo(VI) and V(V) show them to be CrO2− 4, oxine-Mo peroxo and oxine-V-bipyridine peroxo complexes, respectively, and were used for the separation, identification and determination of Cr(VI), Mo(VI) and V(V) using acetonitrile-water as mobile phase. The calibration curves obtained for 20 μl injections were linear for 1.4–7.0 mg/l Cr, 1.3–6.5 mg/l Mo and 0.7–3.4 mg/l V. The relative standard deviations were between 6 and 10%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. White PC (1984) Analyst 109:677

    Google Scholar 

  2. Lajunen LHJ, Eigarvi E, Kenakkala T (1984) Analyst 109:699

    Google Scholar 

  3. Hoffmann BW, Schwedt G (1982) J High Res Chromatogr, Chromatogr Comm 5:439

    Google Scholar 

  4. Gaetani E, Laureri CF, Mangia A, Parolari G (1976) Anal Chem 48:1725

    Google Scholar 

  5. Gurira RC, Carr PW (1982) J Chromatogr Sci 20:461

    Google Scholar 

  6. Schwedt G, Budde R (1982) Chromatographia 15:527

    Google Scholar 

  7. Moriyasu M, Hashimoto Y, Endo M (1981) Bull Chem Soc 54:3369

    Google Scholar 

  8. Wünsch G (1976) Optische Analysenmethoden zur Bestimmung anorganischer Stoffe, de Gruyter, Berlin New York

    Google Scholar 

  9. Hartkamp H (1959) Fresenius Z Anal Chem 171:262

    Google Scholar 

  10. Jahr KF (1941) Z Elektrochem 47:810

    Google Scholar 

  11. Weissler A (1945) Ind Eng Chem Anal Ed 17:698

    Google Scholar 

  12. Eberle AR, Lerner MW (1962) Anal Chem 34:627

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Shanghai Institute of Mechanical Engineering, 516 Jun Gong Lu, 200093, Shanghai, People's Republic of China

    Yi-he Wu

  2. Institute of Food and Analytical Chemistry, University of Stuttgart, Pfaffenwaldring 55, D-7000, Stuttgart 80, Federal Republic of Germany

    Georg Schwedt

Authors
  1. Yi-he Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Georg Schwedt
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wu, Yh., Schwedt, G. HPLC analysis of Cr, V and Mo using pre- in combination with on-column derivatisation by oxine, bipyridine and H2O2 . Z. Anal. Chem. 329, 39–42 (1987). https://doi.org/10.1007/BF00487538

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00487538

Keywords

Search

Navigation