Chemistry of Heterocyclic Compounds

, Volume 8, Issue 6, pp 770–772 | Cite as

Heterocyclic nitro compounds

XV. Kinetics of the reaction of 1-methyl-3-nitro-5-halo-1,2,4-triazoles with hydroxide ions
  • M. S. Pevzner
  • V. Ya. Samarenko
  • L. I. Bagal
Article
  • 28 Downloads

Abstract

The kinetics of the reaction of 1-methyl-3-nitro-5-chloro-1,2,4-triazoles and 1-methyl-3-nitro-5-bromo-1,2,4-triazoles with hydroxide ions were studied. The reaction leads to replacement of the halogen or nitro group, and the ratio of the rates of substitution is 30∶1. The mutual influence of the halogen and nitro group on the rate of substitution as a function of their position in the ring was examined.

Keywords

Hydroxide Organic Chemistry Triazole Halogen Nitro Group 

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Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • M. S. Pevzner
    • 1
  • V. Ya. Samarenko
    • 1
  • L. I. Bagal
    • 1
  1. 1.Lensovet Leningrad Technological InstituteUSSR

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