Chemistry of Heterocyclic Compounds

, Volume 8, Issue 6, pp 770–772 | Cite as

Heterocyclic nitro compounds

XV. Kinetics of the reaction of 1-methyl-3-nitro-5-halo-1,2,4-triazoles with hydroxide ions
  • M. S. Pevzner
  • V. Ya. Samarenko
  • L. I. Bagal


The kinetics of the reaction of 1-methyl-3-nitro-5-chloro-1,2,4-triazoles and 1-methyl-3-nitro-5-bromo-1,2,4-triazoles with hydroxide ions were studied. The reaction leads to replacement of the halogen or nitro group, and the ratio of the rates of substitution is 30∶1. The mutual influence of the halogen and nitro group on the rate of substitution as a function of their position in the ring was examined.


Hydroxide Organic Chemistry Triazole Halogen Nitro Group 
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Literature cited

  1. 1.
    M. S. Pevzner, V. Ya. Samarenko, and L. I. Bagal, Khim. Geterotsikl. Soedin., 568 (1972).Google Scholar
  2. 2.
    L. I. Bagal, M. S. Pevzner, and V. Ya. Samarenko, Khim. Geterotsikl. Soedin., 1701 (1970).Google Scholar
  3. 3.
    S. Benson, Foundations of Chemical Kinetics, McGraw-Hill (1960).Google Scholar
  4. 4.
    M. S. Pevzner, V. Ya. Samarenko, and L. I. Bagal, Khim. Geterotsikl. Soedin., 117 (1972).Google Scholar
  5. 5.
    S. M. Shein and L. A. Kozorez, Reakts. Sposobnost' Organ. Soedin., 3, 45 (1966).Google Scholar
  6. 6.
    S. D. Ross, Modern Problems of Physical Organic Chemistry [Russian translation], Mir, Moscow (1967), p. 33.Google Scholar
  7. 7.
    J. Murto and L. Kaarialainen, Suomen Kemistilehti, B39, 40 (1966).Google Scholar
  8. 8.
    E. Tommila and J. Murto, Acta Chem. Scand., 16, 53 (1962).Google Scholar
  9. 9.
    R. M. Johnson, J. Chem. Soc., B, 1058 (1966).Google Scholar
  10. 10.
    M. Liveris and J. Miller, J. Chem. Soc., 3486 (1963).Google Scholar
  11. 11.
    J. F. Bunnett, E. W. Garbisch, and K. M. Pruitt, J. Am. Chem. Soc., 79, 385 (1957).Google Scholar
  12. 12.
    V. V. Mel'nikov, M. S. Pevzner, V. V. Stolpakova, and L. F. Khor'kova, Khim. Geterotsikl. Soedin., 409 (1971).Google Scholar
  13. 13.
    V. A. Klimova, Fundamental Micromethods for the Analysis of Organic Compounds [in Russian], Khimiya, Moscow (1967), p. 115.Google Scholar

Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • M. S. Pevzner
    • 1
  • V. Ya. Samarenko
    • 1
  • L. I. Bagal
    • 1
  1. 1.Lensovet Leningrad Technological InstituteUSSR

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