Chemistry of Heterocyclic Compounds

, Volume 26, Issue 5, pp 587–591 | Cite as

Synthesis of macroheterocyclic analogs of dibenzocrown ethers. 5. 16- and 17-Membered oxaazacrown ethers

  • A. A. Formanovskii
  • I. V. Mikhura
Article
  • 34 Downloads

Abstract

Macrocyclic diamides are synthesized by condensation of 1,5-bis(2-aminophenyl)-1,5-dioxapentane and 1,6-bis(2-aminophenyl)-1,6-dioxahexane with the dichlorides of glutaric, diglycolic, thiodiglycolic, and N-tosyliminodiacetic acids under high dilution conditions. Reduction with diborane gives the 16- and 17-membered dibenzodiazacrown ethers. The structure of the compounds synthesized is confirmed by IR,NMR (1H and 13C), and mass spectral data.

Keywords

Ether Organic Chemistry Spectral Data Dichloride High Dilution 

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Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • A. A. Formanovskii
    • 1
  • I. V. Mikhura
    • 1
  1. 1.V. I. Vernadskii Institute of Geochemistry and Analytical ChemistryAcademy of Sciences of the USSRMoscow

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