Chemistry of Heterocyclic Compounds

, Volume 26, Issue 5, pp 557–560 | Cite as

Synthesis of 2- and 4-Nitropyrimidines and 2-Nitro-sym-triazines by ozonization of hydroxyamino and nitroso derivatives

  • G. G. Moskalenko
  • V. F. Sedova
  • V. R. Akhmetova
  • V. N. Odinokov
  • V. P. Mamaev
Article

Abstract

The action of ozone on aryl(methyl)-substituted 2- and 4-hydroxyamino- or -nitrosopyrimidines in chloroform gave 2- and 4-nitropyrimidines. The unambiguous character of the process depends on the molar ratio of the substrate and ozone; the side formation of azoxy-, chloro-, and hydroxypyrimidines is possible. 2-Nitro-sym-triazines were obtained by ozonization of substituted 2-hydroxyamino-sym-triazines.

Keywords

Methyl Organic Chemistry Chloroform Ozone Chloro 

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Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • G. G. Moskalenko
    • 1
    • 2
  • V. F. Sedova
    • 1
    • 2
  • V. R. Akhmetova
    • 1
    • 2
  • V. N. Odinokov
    • 1
    • 2
  • V. P. Mamaev
    • 1
    • 2
  1. 1.Institute of Organic Chemistry, Siberian BranchAcademy of Sciences of the USSRNovosibirsk
  2. 2.Institute of Chemistry, Bashkir Science Center, Ural BranchAcademy of Sciences of the USSRUfa

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