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Synthesis and structure of quaternary salts of acridinylhetarylmethanes and their anhydro bases

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Quaternary salts of 9-acridinylhetarylmethanes were obtained by condensation of acridine with alkiodides of 2- and 4-methyl derivatives of nitrogen heterocycles in the presence of air oxygen. A study of the spectra of the acridinylhetarylmethanes and their quaternary salts and anhydro bases indicates tautomeric transfer of the hydrogen atom of the methylene group to the nitrogen atom of the acridine fragment in monoquaternized acridinylhetarylmethanes.

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Literature cited

  1. V. E. Posazhennikova, O. N. Chupakhin, and I. Ya. Postovskii, Khim. Geterotsikl. Soedin., 1384 (1970).

  2. A. Albert, The Acridines, Arnold Press, London (1966).

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  3. G. Scheibe and E. Daltrozzo, in: Advances in Heterocyclic Chemistry, Vol. 7, New York-London (1966), p. 153.

  4. I. Ya. Postovskii, V. E. Posazhennikova, O. N. Chupakhin, and E. P. Darienko, Khim. Geterotsikl. Soedin., 1090 (1971).

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Authors and Affiliations

  1. S. M. Kirov Ural Polytechnic Institute, Sverdlovsk

    O. N. Chapakhin, V. E. Kirichenko & I. Ya. Postovskii

Authors
  1. O. N. Chapakhin
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  2. V. E. Kirichenko
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  3. I. Ya. Postovskii
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1116–1120, August, 1974.

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Chapakhin, O.N., Kirichenko, V.E. & Postovskii, I.Y. Synthesis and structure of quaternary salts of acridinylhetarylmethanes and their anhydro bases. Chem Heterocycl Compd 10, 970–973 (1974). https://doi.org/10.1007/BF00487122

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  • DOI: https://doi.org/10.1007/BF00487122

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