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A study on the effect of the source line profile in atomic magneto-optical rotation spectroscopy (AMORS), using a Zeeman-shifted hollow cathode lamp

Untersuchung der Wirkung des Linienprofils der Lichtquelle in der magneto-optischen Atomrotations-Spektroskopie (AMORS) mit Hilfe einer Hohlkathodenlampe mit Zeeman-Verschiebung

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Zusammenfassung

Mit Hilfe einer magnetisierten Hohlkathodenlampe als Lichtquelle mit Zeeman-Verschiebung wurden die Wirkungen des Linienprofils der Lichtquelle auf die Intensität der Rotationsstrahlung und auf die Eichkurve untersucht. Mit Änderung des Linienprofils ergab sich eine Intensitätssteigerung der Rotationsstrahlung bis zu 40%. Abweichungen der Eichkurve konnten durch geeignete Wahl der magnetischen Feldstärken am Atomizer und der Hohlkathodenlampe vermieden werden.

Summary

Using a magnetized hollow cathode lamp as a Zeeman-shifted light source, the effects of the source line profile on the intensity of rotatory radiation and the calibration curve were studied for AMORS (atomic magneto-optical rotation spectroscopy). With the alteration of the source line profile, an increase in the intensity of rotatory radiation by about max. 40% was found. The rollover of the calibration curve could be avoided by selecting the strengths of the magnetic fields applied to the atomizer and the hollow cathode lamp.

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References

  1. Kitagawa K, Shigeyasu T, Takeuchi T (1978) Analyst 103:1021

    Google Scholar 

  2. Kitagawa K, Koyama T, Takeuchi T (1979) Analyst 104:822

    Google Scholar 

  3. Kitagawa K, Shigeyasu T, Takeuchi (1979) Spectrochim Acta 34B:389

    Google Scholar 

  4. Kitagawa K, Nanya T, Tsuge S (1981) Spectrochim Acta 36B:9

    Google Scholar 

  5. Kitagawa K, Suzuki M, Aoi N, Tsuge S (1981) Spectrochim Acta 35B:21

    Google Scholar 

  6. Kitagawa K, Aoi N, Tsuge S (1981) Nippon Kagaku Kaishi 1981:40

    Google Scholar 

  7. Ito M, Murayama S, Kayama K, Yamamoto M (1977) Spectrochim Acta 32B:347

    Google Scholar 

  8. Stephens R (1979) Can J Spectrosc 24:105

    Google Scholar 

  9. Yamamoto M, Murayama S, Ito M, Yasuda M (1980) Spectrochim Acta 35B:43

    Google Scholar 

  10. Kankare J, Stephens R (1980) Spectrochim Acta 35B:849

    Google Scholar 

  11. Kersey AD, Dawson JB, Ellis DJ (1980) Spectrochim Acta 35B:865

    Google Scholar 

  12. Ito M (1980) Anal Chem 52:1592

    Google Scholar 

  13. Hirokawa K (1980) Anal Chem 52:1966

    Google Scholar 

  14. Hirokawa K, Namiki M (1981) Spectrochim Acta 36B:649

    Google Scholar 

  15. Debus H, Hanle W, Scharmann A, Wirz P (1981) Spectrochim Acta 36B:1015

    Google Scholar 

  16. Kersey AD, Dawson JB (1981) Anal Proc R Soc 18:187

    Google Scholar 

  17. Wirz P, Debus H, Hanle W, Scharmann A (1982) Spectrochim Acta 37B:1013

    Google Scholar 

  18. Stephens R (1983) Spectrochim Acta 38B:1077

    Google Scholar 

  19. Kankare J, Stephens R (1983) Spectrochim Acta 38B:1301

    Google Scholar 

  20. Jolly GS, Stephens R (1984) Spectrochim Acta 39B:335

    Google Scholar 

  21. Murry GF, Stephens R (1978) Talanta 25:223

    Google Scholar 

  22. Ohishi K, Arai Y, Murayama S, Fukuda K (1980) Spectrochim Acta 35B:155

    Google Scholar 

  23. Grassam E, Dawson JB, Ellis DJ (1977) Analyst 108:804

    Google Scholar 

  24. Liddel PR, Brodie KG (1980) Anal Chem 52:1256

    Google Scholar 

  25. deLoos-Vollebrecht MTC, deGalan L (1982) Spectrochim Acta 37B:659

    Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University, Furo-cho, Chikusa-ku, 464, Nagoya, Japan

    Kuniyuki Kitagawa & Tetsuro Noguchi

Authors
  1. Kuniyuki Kitagawa
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  2. Tetsuro Noguchi
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Kitagawa, K., Noguchi, T. A study on the effect of the source line profile in atomic magneto-optical rotation spectroscopy (AMORS), using a Zeeman-shifted hollow cathode lamp. Z. Anal. Chem. 321, 436–441 (1985). https://doi.org/10.1007/BF00487075

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  • DOI: https://doi.org/10.1007/BF00487075

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